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Here,we present the synthesis and electrochemical applications of S-doped porous carbons(SPCs)and 3D networks composing of S and N dual-doped graphene(SNG)and S-doped carbon nanotubes(SCNTs).SPCs with up to 29 wt%S were synthesized based on the S doping reaction between carbon and magnesium sulphate[1].The high concentration S doping was able to significantly enhance the electrical conductivity.