【摘 要】
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Isocyanides have been recognized as versatile building blocks in Lewis or Bronsted acid-promoted reactions, including Passerini and Ugi mutlicomponent reactions
【机 构】
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StateKeyLaboratoryofRespiratoryDisease,GuangzhouInstitutesofBiomedicineandHealth,ChineseAcademyofSci
【出 处】
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中国化学会全国第十一届有机合成化学学术研讨会
论文部分内容阅读
Isocyanides have been recognized as versatile building blocks in Lewis or Bronsted acid-promoted reactions, including Passerini and Ugi mutlicomponent reactions, complex amide synthesis and others.However, their application in transition-metal-catalyzed imination, carboxyamidation, amidination reactions, and cyanation, acting as isoelectronic equivalents of CO, is relatively undervalued.[1] In this conference, we will report our recent research on some new reactions involving imidoyl palladium and imidoyl radical intermediates for the synthesis ofN-heterocycles.
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