具有可调电催化性能的meso位和轴向位修饰的的IrⅢ三芳基咔咯

来源 :The First Asian Conference on Porphyrins, Phthalocyanines an | 被引量 : 0次 | 上传用户：nini863700

【摘要】

：

报道了三种不同吸电子能力的meso位修饰的内消旋A2B型Ir(Ⅲ)三芳基咔咯的以及三种具有不同吸电子能力的轴向修饰的A3型Ir(Ⅲ)三苯基吡咯的合成及其结构表征。通过将它们的光学光谱学和电化学与DFT和TD-DFT计算中预测的趋势进行比较，以及光学和氧化还原性质的结构性质关系的分析。

【作者】

：

王宇张锡凤朱卫华梁旭

【机构】

：

江苏大学化学化工学院,江苏镇江,212013 江苏大学化学化工学院,江苏镇江,212013

【出处】

：

The First Asian Conference on Porphyrins, Phthalocyanines an

【发表日期】

：

2019年3期

【关键词】

：

咔咯铱电催化 ORRs

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具有可调电催化性能的meso位和轴向位修饰的的IrⅢ三芳基咔咯

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