Lanthanide clusters have been widely applied to molecular magnetic materials,such as single molecule magnets and magnetic coolers,owing to their distinctive and novel structures[1,2].
Three hexacoordinated octahedral nickel(Ⅱ)complexes,[Ni(sal-L-phe)(phen)(CH3OH)](1),[Ni(naph-L-phe)(phen)]CH3OH(2)and [Ni(o-van-L-phe)(phen)(CH3OH)]·5H2O(3)(sal-L-phe = a Schiff base derived from sali
Single-chain magnets(SCMs)have received wide attention because of their potential applications in high-density information storage and quantum computation.
High-nuclearity lanthanide-transition(3d-4f)metal clusters are a unique class of molecule,due to their nanoscopic molecule size,fascinating structure,and interesting chemical properties [1].
With intriguing structures and potential applications in the fields of photoluminescence,catalysis,molecular magnet,and so on,coordination polymers(CPs)have continuously attracted widespread attention