【摘 要】
：
In this paper,We synthesized five novel 1D isostructural Zn(Ⅱ)-lanthanide(Ⅲ)heterometallic complexes[LnZn(L)(H2O)(Cl2)]·2DMA·2H2O(Ln=Nd(1),Eu(2),Tb(3),Dy(4),Gd(5))and synthesized seven 1D heterometall
【机 构】
：
Department of Chemistry,Nankai University,Tianjin,300071
论文部分内容阅读
In this paper,We synthesized five novel 1D isostructural Zn(Ⅱ)-lanthanide(Ⅲ)heterometallic complexes[LnZn(L)(H2O)(Cl2)]·2DMA·2H2O(Ln=Nd(1),Eu(2),Tb(3),Dy(4),Gd(5))and synthesized seven 1D heterometallicframeworks[LnCo(L)(H2O)(Cl2)]·2DMA·H2O(Ln=Pr(6),Sm(7),Eu(8),Dy(9),Tb(10),Gd(11),Tm(12))(H3L=4,4,4〞-(2,2,2〞-nitrilotris(methylene)-tris-(1H-benzo imidazole-2,1-diyl)tris(methylene))-tribenzoic acid; DMA=N,N-dimethylacetamide).
其他文献
N-heterocyclic carbenes(NHCs)represent one of the most widely utilized supporting ligands in transition metal(TM)chemistry in the last decades.[1] These complexes have exhibited numerous superior acti
Organotin(Ⅳ)compounds with carboxyl groups have been extensively studied owing to their antitumor activities as well as their diversities in structure[1].
Laminar nanocomposite of LaNb2O7/MnTMPyP [5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato manganese(Ⅲ)] was fabricated via electrostatic interaction between the colloidal dispersion of LaNb2O
酪氨酸蛋白激酶在部分肿瘤细胞发展过程中起到了重要的作用，以其为作用靶点的激酶抑制剂的研究逐渐引起人们的关注。和细胞毒性药物相比，酪氨酸蛋白激酶抑制剂的优势在于其可以高选择性作用于酪氨酸蛋白激酶上和低细胞毒副作用。
Control of the structures of [CunIn] units in Cu(Ⅰ)coordination polymers with 2-pyridyl-functionalized 3-(1H-pyrazolyl)pyridines.
配位分子笼(MOC)由于内部拥有良好的空腔、高对称性和稳定性的结构而吸引越来越多的人关注,并且它们被发现在磁性,催化,气体的分离与储存等方面有着广发的应用.[1] 而设计特定结构的有机配体是构建具有特殊结构与催化效应的分子容器的有效方法.[2] 在本文中,我们设计了双齿螯合的三角架型配体,并通过溶剂热自组装得到两种新颖的异质同晶的M4L4(M=Co2+/Ni2+；L=tris(2-ethanoly
金属有机框架化合物(MOFs)在选择性催化、分子识别、质子导体、发光材料、气体吸附等领域具有潜在的应用价值,受到人们的广泛关注.我们设计合成了一种Y 型配体:9-(2-(乙氧基-羟基-膦酰基)乙基)-9H-咔唑-3,6-二羧酸(H3PCDC).
Both copper and iron are called base metals and played important roles in the post-anaerobic evolution of nature and exists in a large number of enzymes.
A 3D metal-organic framework,[Zn(PAM)(4-bpdb)] ·DMF(1),has been constructed with aπ- electron-rich ligand 4,4-methylenebis(3-hydroxy-2-naphthalenecarboxylic acid)(PAM)and 1,4-bis(4-pyridyl)-2,3-diaza-
Polynuclear lanthanide hydroxide polymers are a class of intriguing substances with varieties of potential applications ranging from luminescent and magnetic materials to homogeneous catalysis.