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钌卡宾不仅是被广泛应用的复分解反应催化剂,也可作为反应底物用于合成许多用途广泛、结构新颖的有机物.2013年我们报道了稳定的钌烯基卡宾化合物1的合成,l在酸性条件下可与缺电子的炔酯、炔酮反应生成吡啶并五元环化合物5——一类中氮茚衍生物[1].
钌烯基卡宾与烷基炔烃反应合成吡啶并六/七元环化合物
【摘 要】
：
钌卡宾不仅是被广泛应用的复分解反应催化剂,也可作为反应底物用于合成许多用途广泛、结构新颖的有机物.2013年我们报道了稳定的钌烯基卡宾化合物1的合成,l在酸性条件下可与缺电子的炔酯、炔酮反应生成吡啶并五元环化合物5——一类中氮茚衍生物[1].
【机 构】
：
厦门大学化学系,厦门361005
【出 处】
：
第十八届全国金属有机化学学术讨论会
【发表日期】
：
2014年5期
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