Convenient synthesis of triphenylphosphanylidene 1',3'-dihydrospiro [cyclopentane-1,2&#039 - 论文文献免费下载

Convenient synthesis of triphenylphosphanylidene 1',3'-dihydrospiro [cyclopentane-1,2'

来源 :中国化学会第十三届全国有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户：qq1123388099

【摘要】

：

【作者】

：

Wen-Jie Qi Ying Han Chao-Guo Yan

【机构】

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College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China

【出处】

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中国化学会第十三届全国有机合成化学学术研讨会

【发表日期】

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2016年8期

【关键词】

：

multicomponent reaction triphenylphosphine electron-deficient alkyne indan-1 3-d

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　　The three-component reaction of triphenylphosphine,dialkyl acetylenedicarboxylate and arylideneindan-1,3-dione in dry DME at zero to room temperature resulted in functionalized 4-(triphenyl-λ5-phosphanylidene)-1,3-dihydrospiro[cyclopentane-1,2-indene]in 65-87% yields.The unusual feature of the reaction is the triphenylphosphanylidene group retaining in the spiro product.

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Convenient synthesis of triphenylphosphanylidene 1',3'-dihydrospiro [cyclopentane-1,2'

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