【摘 要】
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Nickel catalysts have shown unique ligand control of stereoselectivity in the Suzuki–Miyaura cross-coupling of boronates with benzylic pivalates and derivatives involving C(sp3)–O cleavage.The SIMes l
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Nickel catalysts have shown unique ligand control of stereoselectivity in the Suzuki–Miyaura cross-coupling of boronates with benzylic pivalates and derivatives involving C(sp3)–O cleavage.The SIMes ligand produces the stereochemically inverted C–C coupling product,while the PCy3 ligand delivers the retained stereochemistry.
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