Enantioselective palladium-catalyzed allylic alkylation of indoles by a new class of chiral biquinol

来源 :中国化学会第九届全国有机化学学术会议 | 被引量 : 0次 | 上传用户：dandu10

【摘要】

：

　　A newly developed class of quinoline-based chiral biphosphine ligand,6,6'-bis(diphenylphosphino)-5,5'-biquinoline(BIQAP)was synthesized via a simple two-ste

【作者】

：

Jin-PingLu;BinXie;Guo-ShuChen;Yi-XinChen;

【机构】

：

School of Chemistry and Chemical Engineering,Guangzhou University,Guangzhou,510006,China

【出处】

：

中国化学会第九届全国有机化学学术会议

【发表日期】

：

2015年期

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论文部分内容阅读

　　A newly developed class of quinoline-based chiral biphosphine ligand,6,6'-bis(diphenylphosphino)-5,5'-biquinoline(BIQAP)was synthesized via a simple two-step reactions using optically pure BIQOL as starting material and the stereochemical structure of(R)-BIQAP was determined by X-ray crystallography.

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