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5. The Chameleonic Character of Nonheme Iron(Ⅲ)-Iodosylarene Complexes Results in the Elusive Multiple-

The Chameleonic Character of Nonheme Iron(Ⅲ)-Iodosylarene Complexes Results in the Elusive Multiple-

来源 :第十三届全国量子化学会议 | 被引量 : 0次 | 上传用户：sdvfg4gf3fg3

【摘 要】

：

The iron(Ⅲ)-iodosylbenzene complex [FeⅢ(tpena)(PhIO)]2+(1)is revealed by DFT calculat ions to chameleonically convert either to a masked hypervalent FeV–oxo species,or to a masked monomeric PhIO speci

【作 者】

：

Yong Wang 

【机 构】

：

State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics

【出 处】

：

第十三届全国量子化学会议

【发表日期】

：

2017年10期

【关键词】

：

nonheme the one-oxidant mechanism the multiple-oxidant mechanism 

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论文部分内容阅读

　　The iron(Ⅲ)-iodosylbenzene complex [FeⅢ(tpena)(PhIO)]2+(1)is revealed by DFT calculat ions to chameleonically convert either to a masked hypervalent FeV–oxo species,or to a masked monomeric PhIO species by substrate induction to exert oxidation.

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