Transition-metal-catalyzed amination of unactivated C(sp3)-H bond has undergone a breakthrough in recent years.1-2 However,most of them focus on the primary
Dipolar aprotic media such as DMF,NMP,and nitromethane,are commonly used in several useful organic transformations.These solvents are able to create a uniqu
It is well known that the substrate activation strategy with noncovalent interactions has been widely used in the field of asymmetric organic catalysis,whic
Over the past decades,Rhodium(Ⅲ)-catalyzed direct C-H functionalization has been established as a powerful and versatile tool for the synthesis of valuable