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Prior studies revealed that decolorized intermediates could play a role of electron-shuttling mediator to enhance the performance of dye decolorization and bioelectricity generation,this study selected model compounds with auxochromes(e.g.,benezene-1,2-diol,1,2-diaminobenzene)to explore how chemical structure(s)affected color removal and power producing capabilities in microbial fuel cells(MFCs).