1 Results Introduction of functional groups at the frameworks of the centropolyindanes is a non-trivial task since the construction of the rigid and massive skeletons of,e.g.,tribenzotriquinacene and fenestrindane requires well-balanced synthesis strategies[1,2].In the present contribution,some selected examples are presented for the recent multiple functionalization of tribenzotriquinacenes,such as compound 1,and fenestrindanes,such as compound 2,preformed in our laboratory.See Fig.1. 1 Results Introduction of functional groups at the frameworks of the centropolyindanes is a non-trivial task since the construction of the rigid and massive skeletons of, eg, tribenzotriquinacene and fenestrindane requires well-balanced synthesis strategies [1, 2] .In the present contribution , some selected examples are presented for the recent multiple functionalization of tribenzotriquinacenes, such as compound 1, and fenestrindanes, such as compound 2, preformed in our laboratory.