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The title compound has been synthesized by 2-hydroxy-5-bromobenzaldehyde and 4-amino Phe nylethanone oxime in ethanol solution and characterized structurally by X-ray crystallography.The title crystal structure is only built up by the C15H13BrN2O2 molecules, in which all bond lengths are in nor mal ranges.The two benzene rings form a dihedral angle of 43.11 °.There are strong intramolecularO-H.…N hydrogen bonds between the hydroxyl(O2-H2) groups and the Schiff base nitrogen(N2) atoms, with d(N2…O2)=2.615(A).The molecules are held together by two pairs of intermolecularO1-H1…N1and C5-H5…O2 hydrogen bonds, forming an infinite 1D supra molecular structure along the c axis.