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The kaolinite/methanol intercalation composite was prepared with the precursor kaolinite/dimethylsulfoxide composite via multipe displacements intercalation.The structure and thermal stability of the composite were characterized by X-ray diffracfion(XRD) and Fourier transformationinfrared(FT-IR), thermogravimetric-simultaneous differential scanning calorimetry(TG-DSC).