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Porphyrins are widely known as coordination ligands for a variety of metals in the periodic table.Because of the unique interactions between the π-conjugated macrocyclic ligand and orbitals of the central metal,porphyrin metal complexes display various functions.Inspired by the enormous achievement of porphyrin coordination chemistry,we have been engaged in the synthesis of N-confused porphyrinoids and their metal complexes since the discovery.