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5. Theoretical Study on reaction mechanism and enantioselectivity of ring-opening/cyclization of cyclop

Theoretical Study on reaction mechanism and enantioselectivity of ring-opening/cyclization of cyclop

来源 :The 15th ICQC International Congress of Quantum Chemistry(第1 | 被引量 : 0次 | 上传用户：a83017396

【摘 要】

：

N-oxides are a kind of compounds with characteristics of strong polarity and electron-donating ability[1].Fengs group has proved that the chiral N,N-dioxide-Sc(Ⅲ) complex could catalyze ring-opening/c

【作 者】

：

Junming Wang Na Yang Zhishan Su Changwei Hu 

【机 构】

：

Key Laboratory of Green Chemistry and Technology,Ministry of Education,College of Chemistry,Sichuan

【出 处】

：

The 15th ICQC International Congress of Quantum Chemistry(第1

【发表日期】

：

2015年5期

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论文部分内容阅读

N-oxides are a kind of compounds with characteristics of strong polarity and electron-donating ability[1].Fengs group has proved that the chiral N,N-dioxide-Sc(Ⅲ) complex could catalyze ring-opening/cyclization of cyclopropyl ketones with primary amine,affording excellent results[2].

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