Modular Assembly and Guest-Binding Behavior of Biomimetic Coordination Super-Containers

来源 :第七届全国物理无机化学会议 | 被引量 : 0次 | 上传用户:wuyan123
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Container molecules with well-defined hollow structures have attracted significant interest in recent years.These intriguing molecular receptors contain concave surfaces suitable for binding a variety of guests and offer unique chemical micro-environments relevant for a number of applications,including encapsulation of otherwise unstable species,promotion of chemical transformations,storage and separation of gases,transportation of small molecules,and templated formation of monodisperse nanoparticles.
其他文献
Alcohols are class of comparatively greener alkylating reagents in synthesis than the corresponding carbonyl compounds and organohalides.
会议
The CuAAC reaction has received significant attention since its pivotal discovery by the Meldal and Sharpless groups.
会议
Bipyridines and their heteroaromatic analogues are versatile building blocks in natural products,pharmaceuticals,photonic materials,functional polymers,ligands of metal-catalysts and chiral molecules
会议
Fused benzimidazoles,a special kind of N-heterocycle,rep-resent a class of important compounds that display a broad range of biological functions,therefore many synthetic methods have been developed t
会议
Dearomatization of phenols and naphthols through transition metal-catalyzed allylic substitution reaction remains challenging because of both energetic barriers encountered and competition between C-a
会议
To date,among transition-metal catalyzed addition of arylboronic acids and their analogues with α,β-unsaturated compounds,1,4-addition rather than 1,2-addition to the α,β-unsaturated compounds with ar
会议
阴离子与过渡金属阳离子表现出相似的配位化学规律,如特定的配位几何与配位饱合性.近年来,我们发展的一系列多脲配体对四面体含氧酸根,特别是磷酸根离子,展现出良好的配位性能,这类配体通过组合螯合效应和空间匹配效应能够有效而完美的相互作用.
会议
电解水制氢是氢能开发的重要环节.该领域关键问题之一是开发高效、稳定且储量丰富的可替代贵金属Pt的电催化剂.基于钼、钨金属金属元素的电催化剂是可能取代Pt的重要催化剂系列.鉴于钼、钨又是构成多金属氧酸盐的重要金属元素,因此我们拟利用富含丰产元素钼、钨且具有均一纳米尺寸的多酸为前驱体,设计制备新型高效非贵金属电解水制氢催化剂.
会议
Magnetic bistable materials can potentially be used as memory and switch devices.Preparing multifaceted materials by incorporating two or more hysteretic magnetic transitions that respond to different
会议
Photodynamic therapy(PDT) faces the barrier of tumor selectivity,hypoxia-induced drug resistance,and common limitations of the PDT photosensitizers(PSs) such as water-solubility,premature leaking,bios
会议