理论与试验研究PdO表面修饰对LSCF阴极性能的影响

来源 :第十三届全国量子化学会议 | 被引量 : 0次 | 上传用户:guojinwenv1
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  钯(Pd)金属浸渍La0.6Sr0.4Co0.2Fe0.8O3-δ(LSCF)阴极可提高 LSCF 阴极的氧催化活性1.同时,我们的电化学阻抗测试及原位高温x 衍射光谱(in-situ HT-XRD)试验:发现在700℃ 以下,浸渍Pd 组分以氧化钯(PdO)形式存在,PdO 亦可LSCF 阴极的氧催化活性(Fig.1(a)与(b)).为探究PdO 在LSCF 阴极上的存在方式及提高氧催化活性的机理,我们采用密度泛函理论(DFT)研究了Pd 浸渍对LSCF 阴极的影响.
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