Two novel europium coordination polymers based on fluorine substituted and similar carboxylate ligan

来源 :河南省化学会2016年学术年会 | 被引量 : 0次 | 上传用户:wsykxc1429
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  Two isostructural 3D europium metal–organic frameworks incorporating similar Eu-fluorine substituted carboxylate moieties,{[Eu4(Mimda)4(Tfpa)2·4H2O]}n(1)and {[Eu4(Pimda)4(Tfpa)2·4H2O]}n(2)(Mimda=2-methyl-1H-imidazole-4,5-dicarboxy acid,Pimda = 2-propyl-1H-imidazole-4,5-dicarboxy acid and Tfpa =(3,4,5,6-tetrafluoro-1,2 phthalate acid),have been synthesizedunder hydrothermal conditions.
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