Living anionic polymerisation (LAP) is considered to be a mature topic and although LAP is widely exploited by industry for $billions of sales,it is a technique that currently is not so widely investigated in academia.In the current presentation we will report on recent results on the synthesis of i) Hyperbranched block copolymers via the macromonomer approach1,2 ii) randomly branched polymers via anionic chain transfer polymerisation and iii) copolymers with defined monomer sequence distributions3,4.In each case we will demonstrate how the relatively narrow range of monomers suitable for anionic polymerisation can easily be incorporated into a wide range of molecular architectures with potentially interesting properties and commercial applications.