Direct Observation of Methoxycarbonylnitrene

来源 :第十五届全国化学动力学会议 | 被引量 : 0次 | 上传用户：dfhjaljgjre

【摘要】

：

　　The simplest alkoxycarbonylnitrene,CH3OC(O)N,has been generated through laser(266 and 193 nm)photolysis of CH3OC(O)N3 and CH3OC(O)NCO and subsequently chara

【作者】

：

HongminLi;XiaoqingZeng;

【机构】

：

College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou,Jiangsu,Ch

【出处】

：

第十五届全国化学动力学会议

【发表日期】

：

2017年期

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　　The simplest alkoxycarbonylnitrene,CH3OC(O)N,has been generated through laser(266 and 193 nm)photolysis of CH3OC(O)N3 and CH3OC(O)NCO and subsequently characterized by IR(15N,D-labelling)and EPR(|D/hc| = 1.66 cm–1 and |E/hc| = 0.020 cm–1)spectroscopy in cryogenic matrices.

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Direct Observation of Methoxycarbonylnitrene

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