The reactions of copper(Ⅰ)salts CuX [X = Cl,OTf(OTf = CF3SO3)and ClO4] and bis(diphenylphosphino)methane(dppm)with 4,4-bipyridine(bipy),2,2-bipyridine(bpy),isoquinoline and 1,10-phenanthroline(Phen)le
Metal-organic coordination polymers(MOCP)has promising aspects in areas of gas storage,drug delivery and catalysis owing to their fine-tunable structures[1] and pore size tunability[2].
A novel metal-organic coordination compound,[Zn(μ2-OH)(ATZ)]n(ATZ = 5-amino-1H-tetrazole),has been synthesized through hydrothermal reaction using 5-amino-1H-tetrazole and Zn(NO3)2 as a starting mater
Compound 1 is a linear molecule and the pentafluorobenzene rings are approximately coplanar with the aromatic rings [dihedral angle 5.2°],which promote to form a 2D net.
Porous coordination polymers(PCPs)or metal organic frameworks(MOFs),1 have demonstrated significant promise for gas adsorption and separation because of their chemical tailorability,which results in h
A novel uranyl carboxyphosphonate(H2dipy)[(UO2)3(H2O)2(H2DPTP)2]·2H2O [H6DPTP = 2,5-diphosphonoterephthalic acid,dipy = 4,4-bipyridine] has been synthesized under hydrothermal condition.
During the past two decade,the design and synthesis of coordination polymers have attracted considerable attention because of their intuitive architectures and potential applications [1].