Mechanistic study on metalloporphyrin aerobic catalytic oxidation of cyclohexane using isotope label

来源 :第九届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：hulin510

【摘要】

：

Isotopically labeled water,H218O,has been frequently used as indirect evidence for the high-valent metal oxo intermediates in the catalytic oxygenation reaction

【作者】

：

LIU Qiang Huang Xiaojian QIU Xudong GUO Cancheng

【机构】

：

Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Chang

【出处】

：

第九届全国物理有机化学学术会议

【发表日期】

：

2011年期

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Isotopically labeled water,H218O,has been frequently used as indirect evidence for the high-valent metal oxo intermediates in the catalytic oxygenation reactions of organic substrates by metalloporphyrins,especially with stoichiometric oxidants.

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Mechanistic study on metalloporphyrin aerobic catalytic oxidation of cyclohexane using isotope label

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