Enantiomeric Binaphtyl-brided SALEN Zirconium Complexes as Catalysts for Stereoselective Polymerizat

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1 Results Chiral Schiff-base complexes have been used as catalysts for several stereoselective organic transformations,but they have never been tested for the polymerization of chiral olefins.The preferential polymerization of a single monomeric enantiomer (stereoselective polymerization) pursues two intriguing goals: i) the development of polymeric materials with peculiar optical or physical properties and ii) the kinetic resolution of racemic alkenes. 1 Results Chiral Schiff-base complexes have been used as catalysts for several stereoselective organic transformations, but they have never been tested for the polymerization of chiral olefins. The preferential polymerization of a single monomeric enantiomer (stereoselective polymerization) pursues two intriguing goals: i) the development of polymeric materials with peculiar optical or physical properties and ii) the kinetic resolution of racemic alkenes.
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