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The electronic structures of the stationary points [transition states(TSs)and minima on seam of crossing(MSXs)] for potential energy surfaces(PES)of acetyl fluoride(CH3C(O)F)in the lowest three electronic states(S0,S1,and T1)have been calculated at CASPT2 and RS2-f12 level of theories.Combining with the surface interaction points,the photolysis mechanisms leading to probable photolysis products have been elucidated.