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5. Reversible CO Dissociation of Tricarbonyl Iodide [Fe]-hydrogenase Models Ligating Acylmethylpyridyl

Reversible CO Dissociation of Tricarbonyl Iodide [Fe]-hydrogenase Models Ligating Acylmethylpyridyl

来源 :第十九届全国金属有机化学学术讨论会 | 被引量 : 0次 | 上传用户：zhaoyali_0

【摘 要】

：

[Fe]-hydrogenase can catalyze the activation of H2 in the presence of methenyltetrahydromethanopterin(methenyl-H4MPT+),and its active site contains one Fe atom,

【作 者】

：

胡博文 陈大发 

【出 处】

：

第十九届全国金属有机化学学术讨论会

【发表日期】

：

2016年10期

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[Fe]-hydrogenase can catalyze the activation of H2 in the presence of methenyltetrahydromethanopterin(methenyl-H4MPT+),and its active site contains one Fe atom,which is coordinated by two cis-CO,a cysteine sulfur atom(Cys 176),a labile water,and a bidentate acylmethylpyridinol ligand(Figure 1).

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