【摘 要】
:
Activation of molecular O2 is the most critical step in gold-catalyzed oxidation reactions.Although it is generally accepted that O2 is activated at the interface between Au nanoparticles and supports
【机 构】
:
Institute of Industrial Catalysis,School of Chemical Engineering an d Technology,Xi'an Jiaotong Uni
论文部分内容阅读
Activation of molecular O2 is the most critical step in gold-catalyzed oxidation reactions.Although it is generally accepted that O2 is activated at the interface between Au nanoparticles and supports[1] or at the oxygen defects of reducible oxides[2],an overall understanding of the activation of O2 is still elusive due to the neglect of catalytic environments.
其他文献
Ag2S-montmorillonites nanocomposites(Ag2S-MMT NPs) were synthesized by a facile hydrothermal method.The as-prepared nanocomposites were characterized by X-ray diffraction(XRD),transmission electron mi
ZnS nanoparticles modified with 5,10,15,20-tetrakis(4-carboxyl phenyl)porphyrin were successfully prepared by a simple one-step method.It was demonstrated that the nanocomposites could catalyze the ox
In this paper,ZnS nanoparticles deposited on montmorillonite(ZnS-MMT) were prepared by a facile method at room temperature and characterized by powder X-ray diffraction(XRD),Energy-dispersive X-ray De
On account of the preparation of metal oxide nanomaterials becomes governable and the lattice matching between metal oxides is not difficult to achieve,much research interest has been pointed at multi
A cyclometalated iridium(Ⅲ) complex,[Ir(ppy)2(PCN)]Cl(Ir1,ppy = 2-phenylpyridine,PCN = 2-(4-cyanophenyl)imidazo[4,5-f][1,10]phenanthroline),was synthesized and characterized in the present study.
The structures,relative stabilities,vertical electron detachment energies and magnetic properties of a series of trinuclear clusters are explored via combined broken-symmetry DFT and ab initio study.S
In this article,the reaction mechanisms of the H2S+3O2 formation from the HO2+HS reaction with catalyst X(X=H2O,(H2O)2 and(H2O)3) have been investigated theoretically at the CCSD(T)/6-311++G(3df,2pd)/
Conventional conjugated systems are characteristic of only either inherent or induced chirality because of synthetic challenge in combination of chiral segment into the main chromophore.In this work,c
The consumption of traditional fossil-fuel energy resources cause the increasingly serious environmental problems resulting in the crisis of human sustaining development.The clean and renewable energy
The three-dimensional quantitative structure-selectivity relationship(3D-QSSR) model was developed to investigate the enantioselectivity of the asymmetric ketone hydrogenation(AKH) catalyzed by RuH2(d