邻香草醛肟金属配合物的合成及晶体结构

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:zhusimeng
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  邻羟基肟类配体含有多个O、N 原子,具有很强的配位能力,与不同的金属原子可以形成单核、双核和多核的金属配合物[1-3]。我们合成了邻香草醛肟(H2vanox),并与醋酸铒反应得到了一个三核的配合物[Er3(vanox)4(Hvanox)2(OAc)(MeOH)]·MeOH·3H2O,并通过X-射线单晶衍射、红外光谱、元素分析等进行了结构表征。
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