Fullerenes as one of the most interesting allotrope of carbon have been underdeveloped in energy storage because a high temperature(up to 2000 ℃)or the addition of templates or activators are always n
Transition metal-catalyzed enantioselectiveinsertion of carbenefragments,generated from diazo reagents,into C-H bondprovides a promising,atom-economicalmethod for the formation of C-C bonds.
The development of aromatic compounds and new methods for their construction has been of great interest,due to the fact that such moieties are present in various drugs and in devices used in the field
Azoxy compounds,which have been widely applied in dyes,polymer inhibitors,and stabilizers,are key materials in electronic devices with wonderful liquid crystalline properties.
In fact,we have developed a new NNP-tridentate ruthenium complex as highly efficient catalyst in the coupling cyclizations of γ-aminoalcohols with secondary alcohols.
The stable enamide structure has been found to present in numerous natural products and active drugs.Enamides have been extensively used as versatile building blocks in various organic transformations
Rh(Ⅲ)-catalyzed carbocyclization reactions of 3-(indolin-1-yl)-3-oxopropanenitriles with alkynes and alkenes to form 1,7-fused indolines through C-H activation has been developed.
Nitrogen-containing heterocycles have been received persistent interests for their biological applications.[1] They are of interest because of its own physiological activity,for its relationship to th
The synthesis of isoindolinones has attracted considerable attention owing to their interesting biological and pharmaceutical properties,as well as their usefulness as precursors for the synthesis of