2. 您的位置
3. 首页
4. 会议论文
5. The Chameleonic Character of Nonheme Iron(Ⅲ)-Iodosylarene Complexes Results in the Elusive Multiple-

The Chameleonic Character of Nonheme Iron(Ⅲ)-Iodosylarene Complexes Results in the Elusive Multiple-

来源 :第十三届全国量子化学会议 | 被引量 : 0次 | 上传用户：l00ok100

【摘 要】

：

　　The iron(Ⅲ)-iodosylbenzene complex [FeⅢ(tpena)(PhIO)]2+(1)is revealed by DFT calculat ions to chameleonically convert either to a masked hypervalent FeV–

【作 者】

：

Yong Wang 

【机 构】

：

State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics

【出 处】

：

第十三届全国量子化学会议

【发表日期】

：

2017年期

下载到本地 , 更方便阅读

下载此文 赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

　　The iron(Ⅲ)-iodosylbenzene complex [FeⅢ(tpena)(PhIO)]2+(1)is revealed by DFT calculat ions to chameleonically convert either to a masked hypervalent FeV–oxo species,or to a masked monomeric PhIO species by substrate induction to exert oxidation.

其他文献

Quintuple super bonding between superatoms of metallic clusters

会议

clusters

Flexible Multicenter bonding in closo-BnHn

会议

The nature of d10-s2 interaction in M@(AuSH)6 clusters

会议

Highly active graphene oxide-supported cobalt single-ion catalyst for chemiluminescence reactions

　　Graphene or graphene oxide(GO)-supported single metal atom as effective catalysts for chemical reactions have received extensive research interests.

会议

Understanding Electronic and Structural Phase Transitions for Defect-Induced VO2 Metal-Insulator Tra

　　Oxygen vacancy defect in monoclinic vanadium dioxide has been shown to modulate the metal-insulator transition(MIT)at room temperature.However,the electroni

会议

Towards Design of Room-temperature Phosphorescent Organic Molecules By Enhancing Intersystem Crossin

　　Room-temperature phosphorescent(RTP)materials have attracted an increasing number of scientific explorations because of their significant features,such as l

会议

Strain effect in electrochemical reduction of CO2

　　Tuning the surface strain of heterogeneous catalysts represents a powerful strategy to engineer their catalytic properties b y altering the electronic struc

会议

Steering the Charge Flow in Ternary Semiconductor-(Semic onductor/Metal)Heteronanorods by Unique Arc

　　It has been a long-standing demand to design heteronanostructures(including type-Ⅰ(straddling gap)and type-Ⅱ(staggered gap))for desired charge flow steeri

会议

FlowtheArchitecture Design

Conversion of Dinitrogen to Ammonia

　　Dinitrogen is abundant in atmosphere,yet it can merely be utilized directly by a few organisms with endophytic diazotrophic bacteria.

会议

MD Study on the Interfacial Behaviors of Hydrophilic/Hydrophobic Cyclic Peptide Nanotubes

　　Seven hydrophilic/hydrophobic cyclic peptide nanotubes(CPNTs)were constructed from nine kinds of amino acids,i.e.,Ala(A),Leu(L),Val(V),Ile(I),Trp(W),Gln(Q),

会议