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磷宾(phosphinidene)是卡宾和氮宾的含磷类似物[1].磷宾具有一个单配位的磷原子，该磷原子外层具有16个电子和一个未占据的空轨道(Fig.1).我们基于现代量子化学的计算方法，成功设计并且合成了第一例单线态的膦基磷宾.
单线态磷宾的合成及反应活性
【摘 要】
：
磷宾(phosphinidene)是卡宾和氮宾的含磷类似物[1].磷宾具有一个单配位的磷原子，该磷原子外层具有16个电子和一个未占据的空轨道(Fig.1).我们基于现代量子化学的计算方法，成功设计并且合成了第一例单线态的膦基磷宾.
【机 构】
：
加利福尼亚大学圣地亚哥分校化学与生物化学系,拉霍亚,加利福尼亚 92093-0343,美国;厦门大学化学系,厦门 361005,福建,中国
【出 处】
：
中国化学会第30届学术年会
【发表日期】
：
2016年7期
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