Enantioselective palladium-catalyzed allylic alkylation of indoles by a new class of chiral biquinol

来源 :中国化学会第九届全国有机化学学术会议 | 被引量 : 0次 | 上传用户:XUE19880204
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  A newly developed class of quinoline-based chiral biphosphine ligand,6,6-bis(diphenylphosphino)-5,5-biquinoline(BIQAP)was synthesized via a simple two-step reactions using optically pure BIQOL as starting material and the stereochemical structure of(R)-BIQAP was determined by X-ray crystallography.
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