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A new silver compound of [Ag2(μ2-pip)(Hpip)2](BPDSDC)·10(H2O)(1)(H4BPDSDC = biphenyl-3,3-disulfonyl-4,4-dicarboxylic acid,pip = piperazine)has been synthesized.Single-crystal X-ray diffraction(XRD)indicates that it crystallized in the triclinic system,space group P-1.