【摘 要】
:
The ability of the two dodecahedral cages (D-512 and D-435663) of structure H (sH) hydrate,with t-butylmetylether (TBME) as large cage guest,to discriminate between two guest molecules that are slight
【机 构】
:
Steacie Institute for Molecular Sciences,National Research Council Canada,CANADA;Eindhoven Universit
【出 处】
:
The 8th International Conference on Gas Hydrate(第八届国际天然气水合物大
论文部分内容阅读
The ability of the two dodecahedral cages (D-512 and D-435663) of structure H (sH) hydrate,with t-butylmetylether (TBME) as large cage guest,to discriminate between two guest molecules that are slightly different in size,methane (CH4) and (CH3F),was studied by solid state 13CNMR spectroscopy and molecular dynamics simulation.
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