【摘 要】
：
Boron dipyrromethene(BODIPY)dyes have attracted considerable research attention due to their unique optical property and comprehensive application.[1-2] Alt
【机 构】
：
杭州师范大学,有机硅化学与材料技术教育部重点实验室,浙江杭州,311121
论文部分内容阅读
Boron dipyrromethene(BODIPY)dyes have attracted considerable research attention due to their unique optical property and comprehensive application.[1-2] Although BODIPYs are strong emissive in solution,they are almost nonemissive in the solid state,however,owing to the small Stokes shifts,symmetric and planar structure,which lead to intense intermolecular π-π and self-absorption.[3] For this reason,new types of asymmetrical BF2 complexes have been developed,some of which have shown moderate emission in solid state.
其他文献
有机小分子化合物的分离和鉴别在生物技术、化工以及环境监测等领域中既具有重要意义又富有挑战性.MOFs 多孔性及孔径大小可调特性决定了其本身易于捕捉某些特殊小分子或
Microporous MOFs are current interesting as they open a new door for the design and synthesis of artificial materials with promising properties that can be
基于多核配合物的单分子磁体在高密度信息储存领域有潜在的应用价值。近来,我们致力于多核三异金属配合物的组装,期望得到性能优良的单分子磁体[1,2]。
The rational design and controlled synthesis of metal-organic frameworks(MOFs),has become an exciting field owing to their unique structural characteristics
High-nuclearity lanthanide-transition(3d-4f)metal clusters are a unique class of molecule,due to their nanoscopic molecule size,fascinating structure,and in
利用二甲基二氯化锡与硒代蛋氨酸水杨醛席夫碱，合成了二甲基锡硒代蛋氨酸席夫碱配合物：(CH3)2Sn(L)(1)(L=硒代蛋氨酸席夫碱配体)。通过元素分析、红外光谱IR、核磁共振谱NM
In recent years,boron dipyrromethenes(BODIPYs),have emerged as one of the most important types of chromophore and are probably now the subject of the larges
金属有机框架(MOFs)在气体储存、催化、探针、药物载体等方面有着广泛的应用，近年来吸引了科学家们的注意。但是很多金属有机框架材料稳定性并不好，特别是水稳定性，例如著名
A boron-dipyrromethene(BODIPY)dye is rational designed by adding a styryl substituent with hydroxyl and nitro group,which exhibits a 'turn-on' fluorescence
有机–金属配位化合物因其独特的理化特性,在非线性光学、分子磁体、分子开关、气体的存储与分离等材料学领域有着重要的应用价值。具有良好抗癌活性的配合物—顺铂的发