2. 您的位置
3. 首页
4. 会议论文
5. DFT Study on the Mechanism and Stereoselectivity of the Rh(Ⅱ)-Catalyzed Cyclopropanation of Diazooxi

DFT Study on the Mechanism and Stereoselectivity of the Rh(Ⅱ)-Catalyzed Cyclopropanation of Diazooxi

来源 :第十一届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：dolan525

【摘 要】

：

Motivated by the pronounced biological activity of the spirooxidole-containing compounds, spirocyclic oxindole scaffolds have continued to draw attention in rec

【作 者】

：

Yun-Sheng Xue Yu-Ping Cai Zhao-Xu Chen 

【机 构】

：

InstituteofTheoreticalandComputationalChemistry,KeyLaboratoryofMesoscopicChemistryofMOE,SchoolofChem

【出 处】

：

第十一届全国物理有机化学学术会议

【发表日期】

：

2015年9期

下载到本地 , 更方便阅读

下载此文 赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

Motivated by the pronounced biological activity of the spirooxidole-containing compounds, spirocyclic oxindole scaffolds have continued to draw attention in recent years.

其他文献

Superhydrophobic Surface Templated by Protein Self-Assembly and Emerging Application Towards Protein

Superhydrophobic surfaces have demonstrated their great values in modern material science.As a result, the preparation of such a surface is continuously appeali

会议

A Novel Photoresponsive Film Actuator

Recently, we have developed a novel synthetic method for highly ordered film consisting of carbon nitride polymers.Interestingly, we found that the resultant fi

会议

Ordered Nanoribbons by Simple Self-Assembly of Fully Conjugated Block Copolymers Using Balance of Va

The self-assembly of block-copolymer (BCP) has been proposed as a promising method to form organized structures.Self-assembly of conductive polymers is also int

会议

Asymmetric Latent Carbocation Catalysis with Chiral Trityl Phosphate

Stable carbocations such as tritylium ions have been widely explored as organic Lewis acids catalysts and reagents in organic synthesis.

会议

一些铑催化的偶联反应中反应机理以及金属铑氧化态变化规律的理论研究

过度金属铑催化的偶联反应近些年已被广泛应用于构建新的碳-碳成键和碳-杂原子成键反应中,并取得很好的反应活性、选择性和很高的收率.这类反应的共同特点是,作为催化剂的铑

会议

Regulatory Mechanism of the Enantioselective Intramolecular Enone [2+2] Photocycloaddition Reaction

The asymmetric catalysis of the intramolecular enone [2+2] photocycloaddition has been subject of extensive experimental studies,[1,2] however theoretical insig

会议

Substituent effects on gas-phase homolytic Fe-O and Fe-S bond energies of m-G-C6H4OFe(CO)2(η5-C5H5)

The thermochemistry of organometallic complexes in solution and in the gas phase has been an area of increasing research interest.

会议

茂铁乙炔基取代的偶氮苯衍生物的光电化学性质研究

分子内的电荷转移对二茂铁取代偶氮苯化合物的光电化学性质有着显著的影响[1-2].将用途广泛的刚性构筑块二茂铁乙炔基引入偶氮苯体系中,可以实现在不改变主要功能基团的前提

会议

Theoretical Studies on the Pseudo π-hole Interaction in the M3H6…(NCF)n (M=C, Si, Ge;n =1, 2, 3) Com

The pseudo π-hole interactions, which could be formed between the Cyclopropane and its derivatives M3H6 (M =C, Si, Ge) and F-CN, have attracted more and more a

会议

Theoretical Study on Metal Bis(diphosphine) Complexes Catalyzed CO2 Hydrogenation Outer Coordination

Carbon dioxide is producing with the industry development and becoming an important greenhouse gas.Therefore, fixation and conversion of carbon dioxide are of s

会议