Cationic Rhodium-Catalyzed Kinetic Resolution of Allylic Alcohols through Redox-Isomerization Reacti

来源 :中国化学会第九届全国有机化学学术会议 | 被引量 : 0次 | 上传用户：ayong790401

【摘要】

：

Transition metal-catalyzed isomerization of allylic alcohols is an efficient way for generating saturated carbonyl compounds,which represents an atom-economic and elegant shortcut to valuable carbonyl

【作者】

：

Kai Ren Mengmeng Zhao Xiaomin Xie Zhaoguo Zhang

【机构】

：

Shanghai Jiao Tong University,800 Dongchuan Road,Shanghai 200240,China

【出处】

：

中国化学会第九届全国有机化学学术会议

【发表日期】

：

2015年7期

【关键词】

：

allylic alcohols mono-O-protected-cyclopentene-1 4-diol derivatives kinetic reso

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

其他文献

An Expedient and Divergent Tandem One-Pot Synthesis of Benz[e]indole and Spiro[indene-1,3'-pyrr

An efficient solvent-depended regioselective [3+2]-cycloaddition/iodocyclization cascade reaction of alkyne-tethered chalcones/cinnamates and TosMIC have been developed.

会议

B(C6F5)3:A New Class of Strong and Bulky Lewis Acid for Exo-Selective Intermolecular Diels-Alder Rea

Lewis acid B(C6F5)3 catalyzed the Diels-Alder reactions of multi-substituted open-chain dienes and α,β-enals to afford the desired products with high exo-selectivities was reported.

会议

Synthesis of Functional Multisubstitued Alkenes via Palladium-Catalyzed Cross-Coupling of Enamides w

A palladium-catalyzed intermolecular alkylation of enamides with α-bromo carbonyls was developed.Under the mild reaction conditions,various cyclic and acyclic enamides could react well with α-bromo ca

会议

Zn(OTf)2 as π acid & σ acid:one-pot cycloisomerization/allylic alkylation cascade of N-(propargyl)ar

Previously we combined Au as the π acid and another early transition-metal as a σ acid together and developed a series of bimetallic relay catalysis.

会议

Tandem Metal Relay Catalysis:One-pot Three-component Click Reaction of Azide,Alkyne and Arylhalide t

Transmetalation is a primary organometallic reaction presented in classic cross-coupling reactions.

会议

A Stereoselective Assembly of Dihydropyranone through NHC/LiCl-catalyzed in situ Activation of α,β-U

The carboxylic acids are readily available,more stable compared with enal and the functionalized aldehydes including α-aryloxy acetal aldehydes and halogenated aldehydes employed previously in NHC-cat

会议

An NHC-catalyzed Oxidative γ-Aminoalkylation of Saturated Carboxylic Acids through in situ Activatio

Carboxylic acids y are less liable to enolize than ketone and activated esters,which may avoid the occurrence of the side reaction including aldol condensation,Michael addition and Claisen condensatio

会议

Base-Mediated Decomposition of Amide-Substituted Furfuryl Tosylhydrazones:Synthesis and Cytotoxic Ac

Photolysis and pyrolysis of furfuryl diazomethanes have been reported to produce enynones,presumably via furfuryl carbenes.

会议

Palladium-Catalyzed Dearomatizing Coupling of Aryl Halides with Furfural Tosylhydrazones:A Novel Acc

The indole structure is probably the heterocyclic nucleus that concentrates the most interest because of its presence in a plethora of natural products and molecules with biological activity.

会议

Pd-ZnO Hybrid Nanowire Arrays as Recyclable and High Active Catalyst for 4-Nitrophenol Reduction and

Noble metal nanostructures,such as Ag,Au and Pd,have received considerable attention in diverse organic synthesis as superior catalysts because of their surface-tailorable and size-dependentcatalytic

会议

Cationic Rhodium-Catalyzed Kinetic Resolution of Allylic Alcohols through Redox-Isomerization Reacti

与本文相关的学术论文