【摘 要】
:
A new metal-organic gel(MOG-1) was synthesized by a solvothermal reaction of dirhodium(Ⅱ) tetraacetate(Rh2(OAc)4) and the tricarboxylic acid 4,4,4-[1,3,5-benzenetriyltris(carbonylimino)]tristribenzoic
【机 构】
:
School of Chemistry and Chemical Engineering,Sun Yat-sen University,Guangzhou,510275
【出 处】
:
中国化学会第九届全国有机化学学术会议
论文部分内容阅读
A new metal-organic gel(MOG-1) was synthesized by a solvothermal reaction of dirhodium(Ⅱ) tetraacetate(Rh2(OAc)4) and the tricarboxylic acid 4,4,4-[1,3,5-benzenetriyltris(carbonylimino)]tristribenzoic acid(H3btctb) in DMF/water or DMF/alcohol.
其他文献
The asymmetric hydrogenation synthesis of γ-amino alcohols,which are important building blocks of antipressants in clinic medicine such as(S)-Duloxetine,(R)-Fluoxetine,and(R)-Atomoxetine(Figure 1),has
Benzoin esters,which can be easily obtained by benzoin condensation or cross-benzoin reaction,are of interest in fields ranging from useful synthetic intermediates in organic conversions to important
Organocalcium chemistry has developed rapidly in recent years.Its chemistry mainly concentrates on the synthesis,structure determination,and catalytic application of some well-defined calcium complexe
Organocopper(Ⅰ) compounds play an important role in organometallic chemistry and are often proposed as key intermediates in many Cu-promoted or catalyzed organic synthesis.
As part of our continuous efforts to study on the ynamide chemistry,1-2 we recently reported a Zn-catalyzed tandem alkyne oxidation/C-H functionalization for the highly site-selective synthesis of ver
As part of our continuous efforts to study on the ynamide chemistry,we describe herein a novel gold-catalyzed formal [3+2] cycloaddition between ynamides and fully substituted isoxazoles,leading to th
多取代的烯烃是很多具有生物活性的天然产物和合成药物分子的重要结构单元,受到合成化学家的广泛关注[1].烯胺类化合物因其独特的化学和生物学特性,在医药,农药,染料和材料等领域有重要应用,它也是合成杂环类化合物的有效合成前体[2].
固态有机发光材料在有机光电二极管,生物医药器件,荧光检测等领域应用广泛。因此,具有高效固态发光效率的有机荧光分子的设计合成是材料科学和有机化学的目前的研究热点之一[1]。
近年来,设计和开发各种新型阴离子化学传感器日益受到人们的关注[1-5].在各种各样的阴离子中,硫酸氢根在生物和环境科学中扮演着重要角色.例如HSO4-往往与其它的氧化性离子共存于核废料中,在较高pH值的环境下会转化为毒性的SO42-,并进入到环境中,进而刺激人的皮肤和眼部,甚至造成呼吸麻痹.
Self-assembly of dirhodium(Ⅱ) tetraacetate(Rh2(Oac)4) with a dicarboxylic acid 3,3-(1,3-phenylenebis(ethyne-2,1-diyl))dibenzoic acid(H2pbeddb) gives rise to a metal-organic polyhedron(MOP) containing