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SO2 depolarized electrolysis (SDE) is the pivotal process in the hybrid sulfur process,which is a promising approach for mass hydrogen production without CO2 emission.In order to analyze and optimize the flow-sheet of the HyS process,it is of great importance to firstly modeling and simulates the SDE process in detail.The modeling of gas-feed SDE process was published before and no works on liquid-feed SDE process were published.