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  5. Discrete Mo-O based giant wheel-porphyrin host-guest nanocompositesa new class of promising nonlinea

Discrete Mo-O based giant wheel-porphyrin host-guest nanocompositesa new class of promising nonlinea

来源 :The First Asian Conference on Porphyrins, Phthalocyanines an | 被引量 : 0次 | 上传用户：jeff1986928
【摘 要】
：
　　Reaction of two giant wheel shaped polyoxomolybdates Na15(MoⅥ 126MoⅤ 28O462H14(H2O)70)0.5(MoⅥ 124MoⅤ 28O457H14(H2O)68)0.5·ca.173H2O and Na16[(MoO3)176(
【作 者】
：
Xiaoyu Ren Ting Wang Yunshan Zhou Lijuan Zhang Arshad Iqbal 
【机 构】
：
StateKeyLaboratoryofChemicalResourceEngineering,CollegeofChemistry,BeijingUniversityofChemicalTechno
【出 处】
：
The First Asian Conference on Porphyrins, Phthalocyanines an
【发表日期】
：
2019年11期
【关键词】
：
Porphyrin Polyoxometalate Nanocomposite Nonlinear optical response 
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　　Reaction of two giant wheel shaped polyoxomolybdates Na15(MoⅥ 126MoⅤ 28O462H14(H2O)70)0.5(MoⅥ 124MoⅤ 28O457H14(H2O)68)0.5·ca.173H2O and Na16[(MoO3)176(H2O)63(CH3OH)17H16]·ca.76H2O with 5,10,15,20-zinc tetrahydroxyphenyl porphyrin(ZnTHPP)leading to formation two new host-guest compounds with the formula Na15[(MoⅥ 126MoⅤ 28O462H14(H2O)70)0.5(MoⅥ 124MoⅤ 28O457H14(H2O)68)0.5][C44H28N4O4Zn]3·ca.78H2O(Compound 1)and Na16[(MoO3)176(H2O)63(CH3OH)17H16][C44H28N4O4Zn]3·ca.72H2O(Compound 2).
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