温度导向的锌(Ⅱ)配合物合成及其光[2+2]环加成反应

来源 :中国化学会第30届学术年会 | 被引量 : 0次 | 上传用户:laohe200304
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  光致[2+2]环加成反应是近年来配位化学研究中的热点之一[1,2]。本文报道在不同的温度下通过溶剂热法用硝酸锌与V-型含氮配体(3,5-二(吡啶乙烯基)吡啶)合成了一维配位聚合物[Zn(bpvp)Cl2]n(1)和单核配合物[Zn(Hbpvp)Cl3](2),利用X-射线单晶衍射等技术对它们的结构进行了表征,前者具有手性的一维链状结构,可拆分为具有手性空间群(P43,P41)的对映异构体。
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