Supramolecular polymers, polymeric arrays driven by noncovalent interactions, are of great interests in the field of polymer chemistry and material science.Recently, lots of efforts have been carried out to realize control over supramolecular polymerization by chain growth polymerization, seed polymerization and self-sorting strategy.1 Herein, we are aimed to establish a new method of controllable supramolecualr polymerization through self-sorting of aliphatic and aromatic motifs.