【摘 要】
：
Even inherently brittle hollow silicon nanoparticles (NPs) can withstand larger strain to failure than solid NPs.However,the influence of wall thickness on
【机 构】
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DepartmentofEngineeringMechanics,SVL,Xi'anJiaotongUniversity,Xi'an710049,ChinaDepartmentofChemical
【出 处】
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The 5th Asian Conference on Mechanics of Functional Material
论文部分内容阅读
Even inherently brittle hollow silicon nanoparticles (NPs) can withstand larger strain to failure than solid NPs.However,the influence of wall thickness on the mechanical behavior of hollow Si NPs is not fully understood.Using molecular dynamics simulations,we investigate the compressive behavior of hollow Si NPs.Three distinct failure mechanisms of hollow NPs are uncovered,and their strength and deformability are analyzed quantitatively.For extra-thick-walled NPs,dislocations will nucleate below the contact area and cut through the particles till failure.For mid-thick-walled NPs,however,dislocations will emit from the inner surface and slip towards the outer surface.For thin-walled NPs,elastic buckling is the cause of failure.Compared to solid NPs,hollow NPs with wall thickness being around half of its outer radius can achieve significant improvement in both strength and deformability.
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