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5. Mechanistic insights into the hydrogenation of ethyl acetate to ethanol catalyzed by SNS pincer ruth

Mechanistic insights into the hydrogenation of ethyl acetate to ethanol catalyzed by SNS pincer ruth

来源 :第十一届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：kkk0089

【摘 要】

：

Gusev and co-workers1 reported that the SNS pincer ruthenium complex [(SNS)Ru(Cl)2] could catalyze the hydrogenation of esters under mild conditions.They also p

【作 者】

：

Xiangyang Chen Yuanyuan Jing Xinzheng Yang 

【机 构】

：

InstituteofChemistry,ChineseAcademyofSciences,2ZhongguancunNorthFirstStreet,Beijing100190,P.R.China

【出 处】

：

第十一届全国物理有机化学学术会议

【发表日期】

：

2015年9期

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Gusev and co-workers1 reported that the SNS pincer ruthenium complex [(SNS)Ru(Cl)2] could catalyze the hydrogenation of esters under mild conditions.They also proposed a postulated mechanism for the base-free hydrogenation of ethyl acetate to ethanol catalyzed by [fac-(SNS)Ru(PPh3)(H)2].

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