Calcium hydroxide nanosols for the consolidation of porous building materials-Results from EU-STONEC

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  The main idea of the European STONECORE R&D project(2008 to 2011)was to develop and evaluate nano materials for the use in refurbishment and conservation of historic monuments.A set of different calcium hydroxide("lime")nanoparticles dispersed in alcohols(CaLoSiL(R))available on the market were tested.The general advantages attributed to alcoholic lime dispersions are:compatibility of the consolidant with the original building material,no limitation of penetration due to the particle size,and no mobilisation of soluble salts.The paper mainly reports the evaluation of lime nanosols for consolidation of lime mortar,gypsum stucco,and mural painting layers.In order to achieve a penetration behaviour which is adequate to the pore structure of the substrate the composition of the nanosol as well as its application procedure has to be adjusted.This can be achieved by dilution,additives,or after-treatment of the surface.Apart from structural strengthening of porous structures the lime nanosols were tested for treatment of larger defects such as fissures,cracks,detachment,and delamination.For this purpose the nanosols were modified with additives,fillers,and aggregate.A "modular systems" was developed to meet all these conservation needs.These materials showed sufficient adhesive strength.They proved applicable for the consolidation of severely cracked limestone as well.The developed lime nanosol formulations were applied to test sites at three historic monuments with promising results.Finally,the paper attempts to give an overview of the results which were achieved in the STONECORE project.
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