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  5. Defect Engineering of Mn-based MOFs with Rod-shaped Building Units by Organic Linker Fragmentation

Defect Engineering of Mn-based MOFs with Rod-shaped Building Units by Organic Linker Fragmentation

来源 :中国化学会第七届全国结构化学学术会议 | 被引量 : 0次 | 上传用户：szgang052809
【摘 要】
：
Mn-MOF-74 [Mn2(DOBDC),DOBDC:2,5-dioxido-1,4-benzenedicarboxylic acid] and a new metal-organic framework Mn5(BDC-O)2(BDC-OH)2(FDM-21,BDC-OH:2-hydroxyterephthalic acid) were synthesized and used as temp
【作 者】
：
Doufeng Wu Wenqing Yan Huoshu Xu Erpan Zhang Qiaowei Li 
【机 构】
：
Department of Chemistry,and iChEM(Collaborative Innovation Center of Chemistry For Energy Materials)
【出 处】
：
中国化学会第七届全国结构化学学术会议
【发表日期】
：
2016年7期
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论文部分内容阅读
Mn-MOF-74 [Mn2(DOBDC),DOBDC:2,5-dioxido-1,4-benzenedicarboxylic acid] and a new metal-organic framework Mn5(BDC-O)2(BDC-OH)2(FDM-21,BDC-OH:2-hydroxyterephthalic acid) were synthesized and used as templates to investigate the formation of defects by doping fragmented linkers with reduced coordination sites,which resulted in distinctly increasing of surface area in BDC-OH doped Mn-MOF-74 with respect to defect-free Mn-MOF-74.
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