Mechanistic Investigation for Zinc-mediated Oxidative Coupling of Aldehydes And Alkynes-A Theoretica

来源 :第十届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户:mmghb
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Conjugated ynones are extremely fascinating synthons in modern organic synthesis.Recently, Prof.A.Lei and co-works in Wuhan University find out a direct access to conjugated ynone through zinc-mediated oxidative coupling of terminal alkynes with aldehydes.
其他文献
In order to explore the existence of α-effect in gas-phase SN2@N reactions, and to compare its similarity and difference with the SN2@C counterparts, we have c
会议
功能染料分子因其独特的骨架结构、结构的可设计性、吸收和发射波长的可调节性以及分子本身优异的光热稳定性等众多优点,而被广泛应用于光电材料领域.含功能染料在内的有机三
会议
波长在650-900 nm发射光由于其处于近红外光谱区域,从而避免生物体自发荧光对检测的影响并且对细胞具有较低的光损伤而备受关注.基于罗丹明、多甲基菁、[1]方酸、[2]有机硼化
会议
It is known that hydroxyl radical (OH) play an important role in radiation-induced nucleic acid (DNA/RNA) damage by reacting with nucleic acid components.The da
会议
From a quantum chemistry point of view, many aspects of organic reaction can be reduced to questions about Born-Oppenheimer potential energy surfaces.The molecu
会议
Cross-dehydrogenative coupling (CDC) reactions go beyond traditional cross-couplings and have significantly advanced modem organic synthetic methodologies.Pione
会议
The first Cu-catalyzed oxidative coupling of alkenes and aldehydes was demonstrated.Various aldehydes were utilized as substrates to construct α,β-unsaturated
会议
Unprecedented dioxygen-triggered oxidative radical process was explored using dioxygen as the solely terminal oxidant, realizing aerobic radical oxysulfonylatio
会议
Triarylphosphines are recently found to be effective biomarkers for S-nitrosated proteins (RSNOs).Mechanistic study has been carried out on the reactions of tri
会议
Desferrioxamine (DFO) is a common drug used for the treatment of iron overload.DFO could protect against DNA single strand breaks induced by tetrachlorohydroqui
会议