【摘 要】
：
基于稠环合成方法的发展以及以呋喃环为底物的Diels-Alder 加成反应的研究,对氧杂双环烯烃的开环反应研究取得到了实验研究的广泛兴趣.近几年来,以氧杂双环模板为起始原
【出 处】
：
中国化学会第七届全国分子手性学术研讨会
论文部分内容阅读
基于稠环合成方法的发展以及以呋喃环为底物的Diels-Alder 加成反应的研究,对氧杂双环烯烃的开环反应研究取得到了实验研究的广泛兴趣.近几年来,以氧杂双环模板为起始原料开始被应用于许多天然产物的全合成研究1.其中,Lautens 课题组在这一领域做了许多细致的工作.2000 年,他们发表了第一篇铑催化的氧杂双环烯烃的不对称开环反应,该反应以优秀的非对映选择性、对映选择性得到醇解和氨解产物2.
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