Molecular phosphonate manganese-alkali metal clusters

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：kyn5210

【摘要】

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【作者】

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Min-Le Han Jian Zhang Dong-Sheng Li Lei Zhang

【机构】

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Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,350002;Co

【出处】

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第九届全国无机化学学术会议

【发表日期】

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2015年7期

【关键词】

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manganese-alkali metal clusters phenylphosphonic acid magnetic properties

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　　Transition-metal phosphonate complexes have received a lot of attention in recent years primarily because of their potential applications in material chemistry.1-4 Three new Mn(Ⅲ)complexes with unusual topologies [MMn12ⅢCl(μ3-O)6(H2O)(PhPO3)9(PhPO3H)6(MeOH)6]·(solvent)x [M = K(1),Rb(2),Cs(3)] have been prepared by treatment of MnCl2·4H2O and NBu4nMnO4 with phenylphosphonic acid in the presence of different alkali metal hydrochloride.

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Molecular phosphonate manganese-alkali metal clusters

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